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Inorganic chemistry.
Author
Miessler, Gary L., 1949-
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Format
Book
Language
English
Εdition
Fifth edition / Gary L. Miessler, St. Olaf College, Paul J. Fischer, Macalester College, Donald A. Tarr, St. Olaf College.
Published/Created
Boston : Pearson, [2014]
©2014
Description
xiv, 682 pages : illustrations (some color) ; 26 cm
Availability
Copies in the Library
Location
Call Number
Status
Location Service
Notes
Lewis Library - Course Reserve
QD151.3 .M54 2014
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Lewis Library - Stacks
QD151.3 .M54 2014
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Details
Subject(s)
Chemistry, Inorganic
—
Textbooks
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Chemistry, Inorganic
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Mineralogical chemistry
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Related name
Fischer, Paul J.
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Tarr, Donald A. (Donald Arthur), 1932-2006
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Library of Congress genre(s)
Textbooks
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Series
Pearson advanced chemistry series
Summary note
Featuring a strong physical/molecular orbital approach, this introduction to inorganic chemistry includes solid-state chemistry, updated organometallic and bioorganic chemistry, and a treatment of co-ordination chemistry.
Notes
Includes index.
Bibliographic references
Includes bibliographical references and index.
Contents
Introduction to inorganic chemistry
Atomic structure
Simple bonding theory
Symmetry and group theory
Molecular orbitals
Acid-base and donor-acceptor chemistry
The crystalline solid state
Chemistry of the main group elements
Coordination chemistry i : structures and isomers
Coordination chemistry ii : bonding
Coordination chemistry iii : electronic spectra
Coordination chemistry iv : reactions and mechanisms
Organometallic chemistry
Organometallic reactions and catalysis
Parallels between main group and organometallic chemistry.
ch. 10 Coordination Chemistry II: Bonding (starting p. 357)
10.1. Evidence for Electronic Structures (starting p. 357)
10.1.1. Thermodynamic Data (starting p. 357)
10.1.2. Magnetic Susceptibility (starting p. 359)
10.1.3. Electronic Spectra (starting p. 362)
10.1.4. Coordination Numbers and Molecular Shapes (starting p. 363)
10.2. Bonding Theories (starting p. 363)
10.2.1. Crystal Field Theory (starting p. 364)
10.3. Ligand Field Theory (starting p. 365)
10.3.1. Molecular Orbitals for Octahedral Complexes (starting p. 365)
10.3.2. Orbital Splitting and Electron Spin (starting p. 372)
10.3.3. Ligand Field Stabilization Energy (starting p. 374)
10.3.4. Square-Planar Complexes (starting p. 377)
10.3.5. Tetrahedral Complexes (starting p. 381)
10.4. Angular Overlap (starting p. 382)
10.4.1. Sigma-Donor Interactions (starting p. 383)
10.4.2. Pi-Acceptor Interactions (starting p. 385)
10.4.3. Pi-Donor Interactions (starting p. 387)
10.4.4. The Spectrochemical Series (starting p. 388)
10.4.5. Magnitudes of eσ, eπ, and Δ (starting p. 389)
10.4.6. A Magnetochemical Series (starting p. 392)
10.5. The Jahn-Teller Effect (starting p. 393)
10.6. Four- and Six-Coordinate Preferences (starting p. 394)
10.7. Other Shapes (starting p. 397)
General References (starting p. 398)
Problems (starting p. 399)
ch. 11 Coordination Chemistry III: Electronic Spectra (starting p. 403)
11.1. Absorption of Light (starting p. 403)
11.1.1. Beer-Lambert Absorption Law (starting p. 404)
11.2. Quantum Numbers of Multielectron Atoms (starting p. 405)
11.2.1. Spin-Orbit Coupling (starting p. 411)
11.3. Electronic Spectra of Coordination Compounds (starting p. 412)
11.3.1. Selection Rules (starting p. 414)
11.3.2. Correlation Diagrams (starting p. 415)
11.3.3. Tanabe-Sugano Diagrams (starting p. 417)
11.3.4. Jahn-Teller Distortions and Spectra (starting p. 422)
11.3.5. Applications of Tanabe-Sugano Diagrams: Determining Δ0 from Spectra (starting p. 425)
11.3.6. Tetrahedral Complexes (starting p. 429)
11.3.7. Charge-Transfer Spectra (starting p. 430)
11.3.8. Charge-Transfer and Energy Applications (starting p. 431)
General References (starting p. 434)
Problems (starting p. 434)
ch. 12 Coordination Chemistry IV: Reactions and Mechanisms (starting p. 437)
12.1. Background (starting p. 437)
12.2. Substitution Reactions (starting p. 439)
12.2.1. Inert and Labile Compounds (starting p. 439)
12.2.2. Mechanisms of Substitution (starting p. 441)
12.3. Kinetic Consequences of Reaction Pathways (starting p. 441)
12.3.1. Dissociation (D) (starting p. 442)
12.3.2. Interchange (I) (starting p. 443)
12.3.3. Association (A) (starting p. 443)
12.3.4. Preassociation Complexes (starting p. 444)
12.4. Experimental Evidence in Octahedral Substitution (starting p. 445)
12.4.1. Dissociation (starting p. 445)
12.4.2. Linear Free-Energy Relationships (starting p. 447)
12.4.3. Associative Mechanisms (starting p. 449)
12.4.4. The Conjugate Base Mechanism (starting p. 450)
12.4.5. The Kinetic Chelate Effect (starting p. 452)
12.5. Stereochemistry of Reactions (starting p. 452)
12.5.1. Substitution in trans Complexes (starting p. 453)
12.5.2. Substitution in cis Complexes (starting p. 455)
12.5.3. Isomerization of Chelate Rings (starting p. 456)
12.6. Substitution Reactions of Square-Planar Complexes (starting p. 457)
12.6.1. Kinetics and Stereochemistry of Square-Planar Substitutions (starting p. 457)
12.6.2. Evidence for Associative Reactions (starting p. 458)
12.7. The trans Effect (starting p. 460)
12.7.1. Explanations of the trans Effect (starting p. 461)
12.8. Oxidation-Reduction Reactions (starting p. 462)
12.8.1. Inner-Sphere and Outer-Sphere Reactions (starting p. 463)
12.8.2. Conditions for High and Low Oxidation Numbers (starting p. 467)
12.9. Reactions of Coordinated Ligands (starting p. 468)
12.9.1. Hydrolysis of Esters, Amides, and Peptides (starting p. 468)
12.9.2. Template Reactions (starting p. 469)
12.9.3. Electrophilic Substitution (starting p. 470)
General References (starting p. 471)
Problems (starting p. 472)
ch. 13 Organometallic Chemistry (starting p. 475)
13.1. Historical Background (starting p. 476)
13.2. Organic Ligands and Nomenclature (starting p. 479)
13.3. The 18-Electron Rule (starting p. 480)
13.3.1. Counting Electrons (starting p. 480)
13.3.2. Why 18 Electrons (starting p. 483)
13.3.3. Square-Planar Complexes (starting p. 485)
13.4. Ligands in Organometallic Chemistry (starting p. 486)
13.4.1. Carbonyl (CO) Complexes (starting p. 486)
13.4.2. Ligands Similar to CO (starting p. 493)
13.4.3. Hydride and Dihydrogen Complexes (starting p. 495)
13.4.4. Ligands Having Extended Pi Systems (starting p. 496)
13.5. Bonding between Metal Atoms and Organic Pi Systems (starting p. 500)
13.5.1. Linear Pi Systems (starting p. 500)
13.5.2. Cyclic Pi Systems (starting p. 502)
13.5.3. Fullerene Complexes (starting p. 509)
13.6. Complexes Containing M---C, M=C, and M[≡]C Bonds (starting p. 513)
13.6.1. Alkyl and Related Complexes (starting p. 513)
13.6.2. Carbene Complexes (starting p. 515)
13.6.3. Carbyne (Alkylidyne) Complexes (starting p. 517)
13.6.4. Carbide and Cumulene Complexes (starting p. 518)
13.6.5. Carbon Wires: Polyyne and Polyene Bridges (starting p. 519)
13.7. Covalent Bond Classification Method (starting p. 520)
13.8. Spectral Analysis and Characterization of Organometallic Complexes (starting p. 524)
13.8.1. Infrared Spectra (starting p. 524)
13.8.2. NMR Spectra (starting p. 527)
13.8.3. Examples of Characterization (starting p. 529)
General References (starting p. 534)
Problems (starting p. 534)
ch. 14 Organometallic Reactions and Catalysis (starting p. 541)
14.1. Reactions Involving Gain or Loss of Ligands (starting p. 541)
14.1.1. Ligand Dissociation and Substitution (starting p. 541)
14.1.2. Oxidative Addition and C---H Bond Activation (starting p. 545)
14.1.3. Reductive Elimination and Pd-Catalyzed Cross-Coupling (starting p. 547)
14.1.4. Sigma Bond Metathesis (starting p. 549)
14.1.5. Application of Pincer Ligands (starting p. 549)
14.2. Reactions Involving Modification of Ligands (starting p. 550)
14.2.1. Insertion (starting p. 550)
14.2.2. Carbonyl Insertion (Alkyl Migration) (starting p. 550)
14.2.3. Examples of 1,2 Insertions (starting p. 553)
14.2.4. Hydride Elimination (starting p. 554)
14.2.5. Abstraction (starting p. 555)
14.3. Organometallic Catalysts (starting p. 555)
14.3.1. Catalytic Deuteration (starting p. 556)
14.3.2. Hydroformylation (starting p. 556)
14.3.3. Monsanto Acetic Acid Process (starting p. 561)
14.3.4. Wacker (Smidt) Process (starting p. 562)
14.3.5. Hydrogenation by Wilkinson's Catalyst (starting p. 563)
14.3.6. Olefin Metathesis (starting p. 565)
14.4. Heterogeneous Catalysts (starting p. 570)
14.4.1. Ziegler-Natta Polymerizations (starting p. 570)
14.4.2. Water Gas Reaction (starting p. 571)
General References (starting p. 574)
Problems (starting p. 574)
ch. 15 Parallels between Main Group and Organometallic Chemistry (starting p. 579)
15.1. Main Group Parallels with Binary Carbonyl Complexes (starting p. 579)
15.2. The Isolobal Analogy (starting p. 581)
15.2.1. Extensions of the Analogy (starting p.
Show 146 more Contents items
ISBN
9780321811059
0321811054
9780321891020
0321891023
LCCN
2012037305
OCLC
811600387
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