Inorganic chemistry.

Author
Miessler, Gary L., 1949- [Browse]
Format
Book
Language
English
Εdition
Fifth edition / Gary L. Miessler, St. Olaf College, Paul J. Fischer, Macalester College, Donald A. Tarr, St. Olaf College.
Published/​Created
  • Boston : Pearson, [2014]
  • ©2014
Description
xiv, 682 pages : illustrations (some color) ; 26 cm

Availability

Copies in the Library

Location Call Number Status Location Service Notes
Lewis Library - Course Reserve QD151.3 .M54 2014 Browse related items Request
    Lewis Library - Stacks QD151.3 .M54 2014 Browse related items Request

      Details

      Subject(s)
      Library of Congress genre(s)
      Series
      Pearson advanced chemistry series
      Summary note
      Featuring a strong physical/molecular orbital approach, this introduction to inorganic chemistry includes solid-state chemistry, updated organometallic and bioorganic chemistry, and a treatment of co-ordination chemistry.
      Notes
      Includes index.
      Bibliographic references
      Includes bibliographical references and index.
      Contents
      • Introduction to inorganic chemistry
      • Atomic structure
      • Simple bonding theory
      • Symmetry and group theory
      • Molecular orbitals
      • Acid-base and donor-acceptor chemistry
      • The crystalline solid state
      • Chemistry of the main group elements
      • Coordination chemistry i : structures and isomers
      • Coordination chemistry ii : bonding
      • Coordination chemistry iii : electronic spectra
      • Coordination chemistry iv : reactions and mechanisms
      • Organometallic chemistry
      • Organometallic reactions and catalysis
      • Parallels between main group and organometallic chemistry.
      • ch. 10 Coordination Chemistry II: Bonding (starting p. 357)
      • 10.1. Evidence for Electronic Structures (starting p. 357)
      • 10.1.1. Thermodynamic Data (starting p. 357)
      • 10.1.2. Magnetic Susceptibility (starting p. 359)
      • 10.1.3. Electronic Spectra (starting p. 362)
      • 10.1.4. Coordination Numbers and Molecular Shapes (starting p. 363)
      • 10.2. Bonding Theories (starting p. 363)
      • 10.2.1. Crystal Field Theory (starting p. 364)
      • 10.3. Ligand Field Theory (starting p. 365)
      • 10.3.1. Molecular Orbitals for Octahedral Complexes (starting p. 365)
      • 10.3.2. Orbital Splitting and Electron Spin (starting p. 372)
      • 10.3.3. Ligand Field Stabilization Energy (starting p. 374)
      • 10.3.4. Square-Planar Complexes (starting p. 377)
      • 10.3.5. Tetrahedral Complexes (starting p. 381)
      • 10.4. Angular Overlap (starting p. 382)
      • 10.4.1. Sigma-Donor Interactions (starting p. 383)
      • 10.4.2. Pi-Acceptor Interactions (starting p. 385)
      • 10.4.3. Pi-Donor Interactions (starting p. 387)
      • 10.4.4. The Spectrochemical Series (starting p. 388)
      • 10.4.5. Magnitudes of eσ, eπ, and Δ (starting p. 389)
      • 10.4.6. A Magnetochemical Series (starting p. 392)
      • 10.5. The Jahn-Teller Effect (starting p. 393)
      • 10.6. Four- and Six-Coordinate Preferences (starting p. 394)
      • 10.7. Other Shapes (starting p. 397)
      • General References (starting p. 398)
      • Problems (starting p. 399)
      • ch. 11 Coordination Chemistry III: Electronic Spectra (starting p. 403)
      • 11.1. Absorption of Light (starting p. 403)
      • 11.1.1. Beer-Lambert Absorption Law (starting p. 404)
      • 11.2. Quantum Numbers of Multielectron Atoms (starting p. 405)
      • 11.2.1. Spin-Orbit Coupling (starting p. 411)
      • 11.3. Electronic Spectra of Coordination Compounds (starting p. 412)
      • 11.3.1. Selection Rules (starting p. 414)
      • 11.3.2. Correlation Diagrams (starting p. 415)
      • 11.3.3. Tanabe-Sugano Diagrams (starting p. 417)
      • 11.3.4. Jahn-Teller Distortions and Spectra (starting p. 422)
      • 11.3.5. Applications of Tanabe-Sugano Diagrams: Determining Δ0 from Spectra (starting p. 425)
      • 11.3.6. Tetrahedral Complexes (starting p. 429)
      • 11.3.7. Charge-Transfer Spectra (starting p. 430)
      • 11.3.8. Charge-Transfer and Energy Applications (starting p. 431)
      • General References (starting p. 434)
      • Problems (starting p. 434)
      • ch. 12 Coordination Chemistry IV: Reactions and Mechanisms (starting p. 437)
      • 12.1. Background (starting p. 437)
      • 12.2. Substitution Reactions (starting p. 439)
      • 12.2.1. Inert and Labile Compounds (starting p. 439)
      • 12.2.2. Mechanisms of Substitution (starting p. 441)
      • 12.3. Kinetic Consequences of Reaction Pathways (starting p. 441)
      • 12.3.1. Dissociation (D) (starting p. 442)
      • 12.3.2. Interchange (I) (starting p. 443)
      • 12.3.3. Association (A) (starting p. 443)
      • 12.3.4. Preassociation Complexes (starting p. 444)
      • 12.4. Experimental Evidence in Octahedral Substitution (starting p. 445)
      • 12.4.1. Dissociation (starting p. 445)
      • 12.4.2. Linear Free-Energy Relationships (starting p. 447)
      • 12.4.3. Associative Mechanisms (starting p. 449)
      • 12.4.4. The Conjugate Base Mechanism (starting p. 450)
      • 12.4.5. The Kinetic Chelate Effect (starting p. 452)
      • 12.5. Stereochemistry of Reactions (starting p. 452)
      • 12.5.1. Substitution in trans Complexes (starting p. 453)
      • 12.5.2. Substitution in cis Complexes (starting p. 455)
      • 12.5.3. Isomerization of Chelate Rings (starting p. 456)
      • 12.6. Substitution Reactions of Square-Planar Complexes (starting p. 457)
      • 12.6.1. Kinetics and Stereochemistry of Square-Planar Substitutions (starting p. 457)
      • 12.6.2. Evidence for Associative Reactions (starting p. 458)
      • 12.7. The trans Effect (starting p. 460)
      • 12.7.1. Explanations of the trans Effect (starting p. 461)
      • 12.8. Oxidation-Reduction Reactions (starting p. 462)
      • 12.8.1. Inner-Sphere and Outer-Sphere Reactions (starting p. 463)
      • 12.8.2. Conditions for High and Low Oxidation Numbers (starting p. 467)
      • 12.9. Reactions of Coordinated Ligands (starting p. 468)
      • 12.9.1. Hydrolysis of Esters, Amides, and Peptides (starting p. 468)
      • 12.9.2. Template Reactions (starting p. 469)
      • 12.9.3. Electrophilic Substitution (starting p. 470)
      • General References (starting p. 471)
      • Problems (starting p. 472)
      • ch. 13 Organometallic Chemistry (starting p. 475)
      • 13.1. Historical Background (starting p. 476)
      • 13.2. Organic Ligands and Nomenclature (starting p. 479)
      • 13.3. The 18-Electron Rule (starting p. 480)
      • 13.3.1. Counting Electrons (starting p. 480)
      • 13.3.2. Why 18 Electrons (starting p. 483)
      • 13.3.3. Square-Planar Complexes (starting p. 485)
      • 13.4. Ligands in Organometallic Chemistry (starting p. 486)
      • 13.4.1. Carbonyl (CO) Complexes (starting p. 486)
      • 13.4.2. Ligands Similar to CO (starting p. 493)
      • 13.4.3. Hydride and Dihydrogen Complexes (starting p. 495)
      • 13.4.4. Ligands Having Extended Pi Systems (starting p. 496)
      • 13.5. Bonding between Metal Atoms and Organic Pi Systems (starting p. 500)
      • 13.5.1. Linear Pi Systems (starting p. 500)
      • 13.5.2. Cyclic Pi Systems (starting p. 502)
      • 13.5.3. Fullerene Complexes (starting p. 509)
      • 13.6. Complexes Containing M---C, M=C, and M[≡]C Bonds (starting p. 513)
      • 13.6.1. Alkyl and Related Complexes (starting p. 513)
      • 13.6.2. Carbene Complexes (starting p. 515)
      • 13.6.3. Carbyne (Alkylidyne) Complexes (starting p. 517)
      • 13.6.4. Carbide and Cumulene Complexes (starting p. 518)
      • 13.6.5. Carbon Wires: Polyyne and Polyene Bridges (starting p. 519)
      • 13.7. Covalent Bond Classification Method (starting p. 520)
      • 13.8. Spectral Analysis and Characterization of Organometallic Complexes (starting p. 524)
      • 13.8.1. Infrared Spectra (starting p. 524)
      • 13.8.2. NMR Spectra (starting p. 527)
      • 13.8.3. Examples of Characterization (starting p. 529)
      • General References (starting p. 534)
      • Problems (starting p. 534)
      • ch. 14 Organometallic Reactions and Catalysis (starting p. 541)
      • 14.1. Reactions Involving Gain or Loss of Ligands (starting p. 541)
      • 14.1.1. Ligand Dissociation and Substitution (starting p. 541)
      • 14.1.2. Oxidative Addition and C---H Bond Activation (starting p. 545)
      • 14.1.3. Reductive Elimination and Pd-Catalyzed Cross-Coupling (starting p. 547)
      • 14.1.4. Sigma Bond Metathesis (starting p. 549)
      • 14.1.5. Application of Pincer Ligands (starting p. 549)
      • 14.2. Reactions Involving Modification of Ligands (starting p. 550)
      • 14.2.1. Insertion (starting p. 550)
      • 14.2.2. Carbonyl Insertion (Alkyl Migration) (starting p. 550)
      • 14.2.3. Examples of 1,2 Insertions (starting p. 553)
      • 14.2.4. Hydride Elimination (starting p. 554)
      • 14.2.5. Abstraction (starting p. 555)
      • 14.3. Organometallic Catalysts (starting p. 555)
      • 14.3.1. Catalytic Deuteration (starting p. 556)
      • 14.3.2. Hydroformylation (starting p. 556)
      • 14.3.3. Monsanto Acetic Acid Process (starting p. 561)
      • 14.3.4. Wacker (Smidt) Process (starting p. 562)
      • 14.3.5. Hydrogenation by Wilkinson's Catalyst (starting p. 563)
      • 14.3.6. Olefin Metathesis (starting p. 565)
      • 14.4. Heterogeneous Catalysts (starting p. 570)
      • 14.4.1. Ziegler-Natta Polymerizations (starting p. 570)
      • 14.4.2. Water Gas Reaction (starting p. 571)
      • General References (starting p. 574)
      • Problems (starting p. 574)
      • ch. 15 Parallels between Main Group and Organometallic Chemistry (starting p. 579)
      • 15.1. Main Group Parallels with Binary Carbonyl Complexes (starting p. 579)
      • 15.2. The Isolobal Analogy (starting p. 581)
      • 15.2.1. Extensions of the Analogy (starting p.
      ISBN
      • 9780321811059
      • 0321811054
      • 9780321891020
      • 0321891023
      LCCN
      2012037305
      OCLC
      811600387
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